Burn Your Playhouse Down: the unreleased duets is a collection of never-before-heard duets between George Jones and an illustrious group of guest stars. The recordings range from the mid-70s with his ex-wife, the First Lady of Country Music, Tammy Wynette, to the most recent recording from 2007 with his daughter, Georgette, the only child from the union of George and Tammy.

All of the songs are unreleased tracks from various projects involving different producers and eras of country music. George was aware of some of the songs but others were a total surprise. The biggest surprise was the discovery of an unreleased George and Tammy duet. Epic Records kindly searched their vaults and found "Lovin’ You, Lovin’ Me."